Product ID:ALUMIPREP 33
MSDS Date:04/09/1998
FSC:6850
NIIN:01-096-2274
MSDS Number: BGLPS

PARKER-AMCHEM/HENKEL CORPORATION

32100 STEPHENSON HIGHWAY
MADISON HEIGHTS, MI 48071
US

Emergency Phone: 810-583-9300

Info Phone: 810-583-9300

Preparer: SULINDA LEFFINGWELL

Cage: 84063

PARKER-AMCHEM/HENKEL CORPORATION

MADISON HEIGHTS, MI 48071 US

Telephone: 1-517-263-9430 CHEM EMER18004249300

Cage: 84063

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9596

PHOSPHORIC ACID (SARA 313) (CERCLA)

CAS: 7664-38-2

RTECS: TB6300000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3/3 STEL; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

POTASSIUM FLUORIDE

CAS: 7789-23-3

RTECS: TT0700000

OSHA PEL 2.5 MG/M3 AS F

ACGIH TLV: 2.5 MG/M3 AS F

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY
& GI TRACTS. ACUTE- CORROSIVE TO THE SKIN, EYES & MUCOUS MEMBRANES.
EYE CONTACT MAY CAUSE SEVERE IRRITATION & BURNS. MAY BE HARMFUL OR
FATAL IF ABSORBED THROUGH S KIN. CONTACT WITH THE SKIN; MAY CAUSE
SERVERE IRRITATION AND/OR BURNS. INHALING MIST/VAPORS MAY CAUSE
RESPIRATORY IRRITATION. INGESTION MAY CAUSE SEVERE IRRITATION &
BURNS OF GI TRACT. CHRONIC- PROLON GED OR REPEATED INGESTION MAY
CAUSE FLUORIDE POISONING.
Explanation of Carcinogenicity:NO INFORMATION AVAILABLE FOR PRODUCT.
ACGIH RATES POTASSIUM FLUORIDE AS A CLASS A4-NOT CLASSIFIABLE AS A
HUMAN CARCINOGEN (RELATED TO FLUORIDES).
Effects of Overexposure:EYES-SEVERE IRRITATION, BURNS, BLINDNESS.
SKIN-SEVERE IRRITATION, BURNS. INGESTED-CALCIFICATION OF LIGAMENTS,
SEVERE BONE CHANGES, PAINFUL MOVEMENT, MOTTLING OF THE TEETH,
PULMONARY FIBROSIS, ANEMIA, ANOREXIA, DENTAL EFFECTS, POSSIBLY
DEATH. INHALATION-UPPER AIRWAY EDEMA, WHEEZING, PULMONARY EDEMA,
PNUEMONITIS, RESPIRATORY FAILURE, FLUOROSIS.
Medical Cond Aggravated by Exposure:SKIN IRRITATION MAY BE AGGRAVATED
IN PERSONS WITH EXISTING SKIN LESIONS. MISTS MAY AGGRAVATE ACUTE OR
CHRONIC ASTHMA OR OTHER RESPIRATORY DISEASES.

First Aid:EYES-RINSE IMMEDIATELY WITH PLENTY OF WATER FOR 15 MINUTES.
SEEK IMMEDIATE MEDICAL ATTENTION. SKIN-IMMEDIATELY REMOVE
CONTAMINATED CLOTHES. FLUSH WITH LOTS OF WATER. SEEK IMMEDIATE
MEDICAL ATTENTION. INGESTED-GET IMMEDIATE MEDICAL ATTENTION. DO
NOT INDUCE VOMITING! IF CONSCIOUS, GIVE 1-2 GLASSES WATER OR MILK.
INHALED-REMOVE TO FRESH AIR. SEEK MEDICAL ATTENTION IF SYMTOMS
DEVELOP OR PERSIST.

Flash Point Method:TCC
Flash Point:=62.8C, 145.F
Extinguishing Media:USE MEDIA SUITABLE FOR THE SURROUNDING AREA.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE
CLOTHING INCLUDING SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:FIRE AND EXPLOSION HAZARDS ARE MODERATE
WHEN THIS PRODUCT IS EXPOSED TO HEAT OR FLAME. VAPORS ARE HEAVIER
THAN AIR & MAY TRAVEL ALONG THE GROUND TO SOME DISTANT SOURCE OF
IGNITION & FLASH BACK.

Spill Release Procedures:STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT
RISK. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT & CLOTHING
DURING CLEAN-UP. ABSORB SPILL WITH ABSORBENT MATERIAL. SHOVEL
MATERIAL INTO APPROPRIATE CO NTAINER FOR DISPOSAL. DISPOSE OF
COLLECTED MATRIAL IN ACCORDANCE WITH REGULATIONS.
Neutralizing Agent:SODA ASH

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED & IN A
COOL, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. DO
NOT GET IN EYES, ON SKIN OR CLOTHING. WASH THOROUGHLY AFFTER
HANDLING. DO NOT INHALE VAPORS OR MIS TS. KEEP PPRODUCT AWAY FROM
HEAT, SPARKOR OPEN FLAME. FOR INDUSTRIAL USE ONLY.
Other Precautions:WARNING! CORROSIVE & TOXIC. "EMPTY" CONTAINERS RETAIN
PRODUCT RESIDUE & CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD,
BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERSA TO HEAT,
FLAME, SPARKS, S TATIC ELECTRICITY OR OTHER SOURCES OF IGNITION;
THEY MAY EXPLODE.

Respiratory Protection:IF VENTILATION IS NOT SUFFICIENT TO EFFECTIVELY
PREVENT BUILDUP OF AEROSOLS OR VAPORS, APPROPRIATE NIOSH/MSHA
RESPIRATORY PROTECTION MUST BE PROVIDED.
Ventilation:USE GENERAL VENTILATION AND USE LOCAL EXHAUST WHERE
POSSIBLE, IN CONFINED OR ENCLOSED SPACES.
Protective Gloves:IMPERVIOUS-RUBBER, NEOPRENE.
Eye Protection:CHEMICAL SPLASH GOGGLES WITH FACE SHIELD.
Other Protective Equipment:EYE WASH STATION & EMERGENCY SHOWER SHOULD
BE IN CLOSE PROXIMITY. USE OF IMPERVIOUS APRON & SHOES SUGGESTED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
NOTES TO PHYSICIAN: OCULAR EXPOSURE TO CORROSIVE FLUORIDE COMPUNDS HAS
BEEN TREATED WITH ISOTONIC SODIUM CHLORIDE OR MAGNESIUM CHLORIDE.
DERMAL EXPOSURE HAS BEEN TREATED WITH CALCIUM GLUCONATE OR CALC IUM
CARBONATE GEL APPLIED TOPICALLY TO RELIEVE PAIN AT EXPOSURE SITE.

HCC:C1
Boiling Pt:>93.3C, 200.F
Vapor Pres:N/D
Vapor Density:N/D
Volatile Org Content %:14
Spec Gravity:1.1 - 1.2
pH:<2
Evaporation Rate & Reference:NOT DETERMINED
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID - SLIGHT SOLVENT ODOR
Percent Volatiles by Volume:40- 60

Stability Indicator/Materials to Avoid:YES
THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS
Stability Condition to Avoid:KEEP AWAY FROM HEAT, IGNITION SOURCES AND
INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND/OR
LOW MOLECULAR WEIGHT HYDROCARBONS. MAY LIBERTAE HYDROGEN FLUORIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. THIS
MATERIAL IS A RCRA HAZARDOUS WASTE D002, CORROSIVE.

Toxicological Information:NO INFORMATION AVAILABLE FOR THIS PRODUCT.
THE MAIN OCCUPATIONAL ROUTES OF EXPOSURE TO FLUORIDE COMPOUNDS ARE
INHALATION & INGESTION; HOWEVER, FLUORIDES MAY BE HARMFUL OR FATAL
IF ABSORBED THROUGH THE SKIN. EXPOSURE TO FLUORIDE COMPOUNDS MAY
RESULT IN SEVERE IRRITATION OR BURNS TO THE EYES, SKIN,
GASTROINTESTINAL SYSTEM AND RESPIRATORY SYSTE. CONTACT WITH
FLUORIDE COMPOUNDS MAY NOT BE IMMEDIATELY EVIDENT DUE TO DELAYED
ONSET OF PAIN FOLLOWING EXPOSURE. PHSOPHORIC ACID IS ASEVERE SKIN,
EYE & RESPIRATORY SYSTEM IRRITANT. REPEATED EXPOSURE MAY CAUSE
BRONCHITIS. 2-BUTOXYETHANOL IS HARMFUL ON INGES TION, INHALATION OR
SKIN ABSORPTION

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA AVAILABLE ON PRODUCT. BECAUSE OF LOW PH OF THIS
PRODUCT, IT WOULD BE EXPECTED TO PRODUCE SIGNIFIGANT ECOTOXICITY
UPON EXPOSURE TO AQUATIC ORGANISMS & AQUATIC SYSTEMS. COMPONENT
ANALYSIS: ETHYL ENE GLYCOL N-BUTYL ETHER (2-BUTOXYETHANOL): LC 50
(96 HR) BLUEGILL: 1490 MG/L. COND: STATIC, 23 DEGREES C; LC 50 (24
HR) GOLDFISH: 1650-1700 MG/L; LC50 (24 HR) WATER FLEA: 1720 MG/L.
ENVIRONEMNTAL FAT E: NO DATA AVAILABLE CONCERNING THE ENVIRONMENTAL
FATE, BIODEGRADATION OR BIOCONCENTRATION FOR THIS PRODUCT.

Transport Information:PLEASE REFER TO THE CONTAINER LABEL FOR
TRANSPORTATION INFORMATION.

SARA Title III Information:ETHYLENE GLYCOL N-BUTYL ETHER (CAS#
111-76-2): SARA 313 : FORM R REPORTING REQUIRED FOR 1% DEMINIMUS
CONCENTRATION. PHOSPHORIC ACID (CAS # 7664-38-2): FORM R REPORTING
REQUIRED FOR 1% DEMINIMUS CONCEN TRATION. SARA 311/312: ACUTE: YES;
CHRONIC: YES; FIRE: YES; PRESSURE: NO; REACTIVE: NO.
Federal Regulatory Information:THIS MATERIAL IS A RCRA HAZARDOUS WASTE
D002, CORROSIVE. CERCLA: ETHYLENE GLYCOL N-BUTYL ETHER- STATUTORY
RQ=1 POUND ( 0.454 KG). PHOSPHORIC ACID: FINAL RQ = 5000 LBS (2270
KG). ALL COMPONENTS ARE ON THE US EPA TSCA INVENTORY LIST.
State Regulatory Information:NO GENERAL PRODUCT INFORMATION. COMPONENT
ANALYSIS - STATE: ETHYLENE GLYCOL N-BUTYL ETHER CAS #
111-76-2-CA-YES; FL-YES, MA-YES, NJ-YES, PA-YES; PHOSPHORIC ACD CAS
# 7664-38-2- CA-YES, FL-YES, MA-YES, MN-YES, NJ-YES, PA-YES;
POTASSIUM FLUORIDE (RELATED TO FLUORIDES) CAS # 7789-23-3-- CA-YES,
FL-NO, MA-NO, MN-YES, NJ-YES, PA-YES.